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In order to offer the best possible experience and widen the range of courses on offer in the Sixth Form, Notre Dame Catholic College for the Arts collaborates with the Alsop High School and the North Liverpool Academy as part of the North Central Liverpool Collaborative. In addition, students are able to access the new diploma courses through collaboration with schools in the North Liverpool Partnership.

Notre Dame Catholic College for the Arts continues to maintain its own distinct ethos and the faith-based principles of Catholicism, though, as always, all faiths are respected at the college. For more detailed information about specific courses and what is available in the Sixth Form parents/carers and students should refer to the Collaborative prospectus and coursebook, available from the college secretariat and on the college website.